Project 13

Catalytic alkoxycarbonylation reactions of unsaturated hydrocarbons with CO2 (WP1)

Host institution: Leibniz Institute for Catalysis (LIKAT), Germany
Deadline for application: 1st April 2020
3 PhD year position. Expected start date: Mid 2020.
Remember to read the eligibility criteria here.

Objectives:

  1. Synthesis of Co- and Fe-phosphine complexes
  2. Evaluation of the catalytic activity of these complexes in the reforming process of MeOH and CO2
  3. Testing of active systems in the benchmark reaction of CO2 with biomass-derived reagents ethylene and MeOH
  4. Optimization of reaction conditions for the benchmark reactions and catalytic carboxylations of other olefins
  5. Development of scalable processes and evaluation of industrial viability of the process (at EV)
  6. Training of elements of computational chemistry to gain knowledge on the alkoxycarbonylation mechanism (at EV)
  7. Evaluation of the potential of catalysts obtained from partners for the benchmark process

Expected Results:

  1. Catalytic system that allows for directly adding carbon dioxide to olefins
  2. Mechanistic insights into CO2-based alkoxycarbonylations
  3. Process for MMA (methyl methacrylate) synthesis based on carbon dioxide

Planned secondment(s):

  • AU to Prof. Skrydstrup (3 months): Learn methodologies for preparing labelled compounds (with ESR9).
  • Industrial secondment to EV with Prof. Franke (3 months): Develop a scalable process and train elements of computational chemistry.
But, once this treatment begins individual needs to choose the capsule one order generic levitra hour before involving in copulation. Then he may think why alone sildenafil 100mg is facing these problem. Some people getting viagra might get relief from oral medications, while some prefer vacuum devices, penile pumps, or even vascular surgery. It is Tadalafil which inhibits the functioning of an enzyme known cialis without prescription deeprootsmag.org as nitrogen oxide which stimulates the blood flow to the male reproductive organ, which makes the male reproductive organ involves removal of Nitric Oxide (NO) in your corpus cavernosum at the time when you are looking through the site ensure that the man will continue to have a healthy love life as well.

Enrolment in Doctoral degree(s): Leibniz Institute for Catalysis (LIKAT), Germany

Principal Supervisor: Prof. Matthias Beller (LIKAT)

Questions? Write to us at co2perate@uit.no.