Publications

2024
  • Davies, J.; Lyonnet, J. R.; Carvalho, B.; Sahoo, B.; Day, C. S.; Julia-Hernandez, F.; Duan, Y.; Velasco-Rubio, A.; Obst, M.; Norrby, P.; Hopmann, K. H.; R. Martin. Kinetically-Controlled Ni-Catalyzed Direct Carboxylation of Unactivated Secondary Alkyl Bromides without Chain Walking. J. Am. Chem. Soc. 2024, 146(3), 1753-1759. DOI: 10.1021/jacs.3c11205
  • Sun, H. W.; Ahrens, A.; Batista, G. M. F.; Donlund, B. S.; Ravn, A. K.; Schwibinger, E. V.; Nova, A.; Skrydstrup, T. Solvent-Base Mismatch Enables the Deconstruction of Epoxy Polymers and Bisphenol A Recovery. Green Chem. 2024, 26(2), 815-824. DOI: 10.1039/d3gc03707j
  • Ge, Y.; Huang, W. H.; Ahrens, S.; Spannenberg, A.; Jackstell, R.; Beller, M. Synthesis of Non-Equivalent Diamides and Amido-Esters via Pd-Catalysed Carbonylation. Nat. Synth. 2024, 3, 202-213. DOI: 10.1038/s44160-023-00411-6

2023
  • Bai, Y.; Taarning, E.; Luthra, M.; Lundegaard, L. F.; KaterinoPoulou, A.; Falsig, H.; Nova, A.; Martinez-Espin, J. S. Tracking Lattice Distortions Induced by Defects and Framework Tin in Beta Zeotypes. J. Phys. Chem. C 2023, 127(38), 19278-19289. DOI: 10.1021/acs.jpcc.3c04751
  • Day, C. S.; Ton, S. J.; Kaussler, C.; Hoffmann, D. V.; Skrydstrup, T. Low Pressure Carbonylation of Benzyl Carbonates and Carbamates for Applications in 13C Isotope Labeling and Catalytic CO2 Reduction. Angew. Chem. Int. Ed. 2023, 62, e202308238. DOI: 10.1002/anie.202308238
  • Deziel, A. P.; Gahlawat, S.; Hazari, N.; Hopmann, K. H.; Mercadoa, B. Q. Comparative study of CO2 insertion into pincer supported palladium alkyl and aryl complexes. Chem. Sci. 2023, 14, 8164-8179. DOI: 10.1039/D3SC01459B
  • Huang, W.; Jackstell, R.; Franke, R.; Beller, M. Towards “Homeopathic” Palladium-Catalysed Alkoxycarbonylation of Aliphatic and Aromatic Olefins. Chem. Commun. 2023, 59, 9505-9508. DOI: 10.1039/D3CC02277C
  • Sowiński, M. P.; Gahlawat, S.; Lund, B. A.; Warnke, A.-L.; Hopmann, K. H.; Lovett, J. E.; Haugland, M. M. Conformational Tuning Improves the Stability of Spirocyclic Nitroxides with Long Paramagnetic Relaxation Times. Commun. Chem. 2023, 6, 111. DOI: 10.1038/s42004-023-00912-7
  • Ahrens, A.; Bonde, A.; Sun, H.; Wittig, N. K.; Hammershøj, H. C. D.; Batista, G. M. F.; Sommerfeldt, A.; Frølich, S.; Birkedal, H.; Skrydstrup, T. Catalytic Disconnection of C-O Bonds in Epoxy Resins and Composites. Nature 2023, 617, 730-737. DOI: 10.1038/s41586-023-05944-6
  • Huang, W.; Jackstell, R.; Spannenberg, A.; Beller, M. An Improved Cobalt-Catalysed Alkoxycarbonylation of Olefins using Secondary Phosphine Oxide Promotors. Catal. Sci. Technol. 2023, 13, 24752479. DOI: 10.1039/D3CY00066D
  • Pedersen, S. S.; Batista G. M. F.; Henriksen, M. L.; Hammershøj, H. C. D.; Hopmann, K. H.; Skrydstrup, T. Lignocellulose Conversion via Catalytic Transformations Yields Methoxyterephthalic Acid Directly from Sawdust. JACS Au 2023, 3, 1221-1229. DOI: 10.1021/jacsau.3c00092
  • Batista, G. M. F.; de Castro, P. P. Advances in the Transition Metal Catalyzed Carboxylation of Aryl Electrophiles: a Field Full of Opportunities for the Brazilian Chemical Society. Rev. Virtual Quim. 2023, 15, 334-351. DOI: 10.21577/1984-6835.20230007
  • Day, S. C.; Rentería-Gómez, A.; Ton, S. J.; Gogoi, A. R.; Gutierrez, O.; Martin, R. Elucidating Electron-Transfer Events in Polypyridine Nickel Complexes for Reductive Coupling Reactions. Nat. Catal. 2023, 6, 244-253. DOI: 10.1038/s41929-023-00925-4
  • Hong, W.; Luthra, M.; Jakobsen, J. B.; Madsen, M. R.; Castro, A. C.; Hammershøj, H. C. D.; Pedersen, S. U.; Balcells, D.; Skrydstrup, T.; Daasbjerg, K.; Nova, A.  Exploring the Parameters Controlling Product Selectivity in Electrochemical CO2 Reduction in Competition with Hydrogen Evolution Employing Manganese Bipyridine Complexes. ACS Catal. 2023, 13, 3109-3119. DOI: 10.1021/acscatal.2c05951
  • Ton, S.J.; Ravn, A. K.; Hoffmann, D. V.; Day, C. S.; Kingston, L.; Elmore, C. S.; Skrydstrup, T. Rapid Access to Carbon-Isotope-Labeled Alkyl and Aryl Carboxylates Applying Palladacarboxylates. JACS Au 2023, 3, 756-761. DOI: 10.1021/jacsau.2c00708
  • Hammershøj, H. C. D.; Gudmundsson, H. G.; Kjærsgaard, S.; Bønnelykke, J.; Kolodiazhnaia, J.; Skrydstrup, T. Multi-Carbon Labelling of Active Pharmaceutical Ingredients Enabled by a Three-Gas Surrogate Hydroformylation. Nat. Synth. 2023, 2, 243-250. DOI: 10.1038/s44160-022-00223-0

2022
  • Day, C. S.; Ton, S. J.; McGuire, R. T.; Foroutan-Nejad C.; Martin, R. Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes. Organometallics 2022, 41, 2662-2667. DOI: 10.1021/acs.organomet.2c00362
  • Wei, D.; Shi, X.; Sponholz, P.; Junge, H.; Beller, M. Manganese Promoted (Bi)carbonate Hydrogenation and Formate Dehydrogenation: Toward a Circular Carbon and Hydrogen Economy. ACS Cent. Sci. 2022, 8, 1457-1463. DOI: 10.1021/acscentci.2c00723
  • Kopf, S.; Liu, J.; Franke, R.; Jiao, H.; Neumann, H.; Beller, M. Base-Mediated Remote Deuteration of N-Heteroarenes – Broad Scope and Mechanism. Eur. J. Org. Chem. 2022, e202200204. DOI: 10.1002/ejoc.202200204
  • Mühlfenzl, K. S.; Sardana, M.; Skrydstrup, T.; Elmore, C. S. Visible-Light Enabled Late-Stage, Room-Temperature Aminocarbonylation of Aryl Iodides with Labeled Carbon Monoxide. ChemistrySelect 2022, 7, e202203582. DOI: 10.1002/slct.202203582
  • Sardana, M.; Mühlfenzl, K. S.; Wenker, S. T. M.; Åkeson, C.; Hayes, M. A.;  Elmore, C. S.;  Pithani, S. Exploring the Enzyme Catalyzed Synthesis of Isotope Labeled Cyclopropanes. J. Label. Comp. Radiopharm. 2022, 65, 86-100. DOI: 10.1002/jlcr.3962
  • Huang, W.; Tian, X.; Jiao, H.; Jackstell, R.; Beller, M. Iridium-Catalyzed Domino Hydroformylation/Hydrogenation of Olefins to Alcohols: Synergy of Two Ligands. Chem. Eur. J. 2022, 28, e202104012. DOI: 10.1002/chem.202104012

2021
  • Ton, S. J.; Neumann, K. T.; Nørby, P.; Skrydstrup, T. Nickel-Mediated Alkoxycarbonylation for Complete Carbon Isotope Replacement. J. Am. Chem. Soc. 2021, 143, 17816-17824. DOI: 10.1021/jacs.1c09170
  • Davies, J.; Lyonnet, J. R.; Zimin, D. P.; Martin, R. The road to industrialization of fine chemical carboxylation reactions. Chem 2021, 7, 2927-2942. DOI: 10.1016/j.chempr.2021.10.016
  • Davies, J.; Janssen-Müller, D.; Zimin, D. P.; Day, C. S.; Yanagi, T.; Elfert, J.; Martín, R. Ni-Catalyzed Carboxylation of Aziridines en Route to β-Amino Acids. J. Am. Chem. Soc. 2021, 143, 4949-4954. DOI: 10.1021/jacs.1c01916
  • Pedersen, S. S.; Donslund, A. S.; Mikkelsen, J. H.; Bakholm, O. S.; Papp, F.; Jensen, K. B.; Gustafsson, M. B. F.; Skrydstrup, T. A Nickel(II)-Mediated Thiocarbonylation Strategy for Carbon Isotope Labeling of Aliphatic Carboxamides. Chem. Eur. J. 2021, 27, 7114-7123. DOI: 10.1002/chem.202005261
  • Yang, J.; Liu, J.; Ge, Y.; Huang, W.; Ferretti, F.; Neumann, H.; Jiao, H.; Franke, R.; Jackstell, R.; Beller, M. Efficient Palladium-Calalyzed Carbonylation of 1,3-Dienes: Selective Synthesis od Adipates and Other Aliphatic Diesters. Angew. Chem. Int. Ed. 2021, 60, 9527-9533. DOI: 10.1002/anie.202015329
  • Li, Y.; Zhang, C.; Huang, W.; Sun, N.; Hao, M.; Neumann, H.; Beller, M. A General Strategy for the Synthesis of α-Trifluoromethyl- and α-Perfluoroalkyl-β-Lactams via Palladium-Catalyzed Carbonylation. Chem. Sci. 2021, 12, 10467-10473. DOI: 10.1039/D1SC02212A
  • Batista, G. M. F.; de Castro, P. P.; dos Santos, J. A.; Skrydstrup, T.; Amarante, G. W. Synthetic Developments on the Preparation of Sulfides from Thiol-Free Reagents. Org. Chem. Front. 2021, 8, 326-368. DOI: 10.1039/D0QO01226B

2020
  • Yang, J.; Liu, J.; Ge, Y.; Huang, W.; Neumann, H.; Jackstell, R.; Beller, M. Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium-Catalyzed Carbonylation of Allylic Alcohols. Angew. Chem. Int. Ed. 2020, 59, 20394-20398. DOI: 10.1002/anie.202028916
  • Yang, J.; Liu, J.; Ge, Y.; Huang, W.; Schneider, C.; Dühren, R.; Franke, R.; Neumann, H.; Jackstell, R.; Beller, M. A General Platinum-Catalyzed Alkoxycarbonylation of Olefins. Chem. Commun. 2020, 56, 5235-5238. DOI: 10.1039/D0CC00650E