Project 3

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Novel catalytic composites for the use of CO₂ as a one carbon synthon for organic synthesis (WPs 1 and 3)

Host institution: Stockholm University (SU), Sweden
Application Deadline: 17th February

Objectives:

1. Design and synthesize non-precious catalysts for reduction of CO₂ to CO (reduction catalyst)
2. Design and synthesize non-precious carbonylation catalysts (synthetic catalyst)
3. Create catalytic composites formed by a reduction catalyst and a synthetic catalyst
4. Evaluate scope and activity and perform in-situ mechanistic studies
5. Apply developed catalysts in the synthesis of high-value carboxylic acids, esters, amides, and α-ketoamides

Expected Results:

1. A variety of heterogeneous catalysts formed from combination of metal nanoparticles or single-site metal complexes into different materials, including metal-organic frameworks
2. Description of characteristics, mechanistic details, and catalytic activity of the new catalysts
3. A composite that combines a reduction and a synthetic catalyst for the use of CO₂ as a one-carbon synthon

Planned secondments:

• ICIQ with Prof. Martin (3 months): Strategies for non-precious metal-catalyzed CO₂ activation (with ESR1)
• Industrial secondment to AZ, Dr. Elmore (2 months): Optimization of developed carbonylation reactions to industrial settings and application to pharmaceutically relevant systems.

Enrolment in Doctoral degree(s): Stockholm University, Sweden

Principal Supervisor: Prof. Belén Martín-Matute (SU)

Questions? Write to us at co2perate@uit.no.