Project 7

Multicomponent functionalization of π-systems incorporating CO₂ (WP2)

Host institution: University of Zurich (UZH), Switzerland
Application Deadline: 31st May 2020
3 PhD year position. Expected start date: Mid 2020.
Remember to read the eligibility criteria here.

Objectives:

1. Develop a non-precious homogeneous catalytic process for the efficient synthesis of heterocycles using atmospheric CO₂ and readily available π-systems as starting materials
2. Acquire in depth mechanistic understanding on these transformations
3. Evaluate chiral ligands and Lewis acids for enantioselective formation of heterocycles from CO₂.
4. Immobilize catalysts for an improved performance
   

Expected results:

1. Reliable catalytic system for the synthesis of highly functionalized CO₂-containing heterocycles from π-systems (alkenes/allenes/alkynes)
2. Mechanistic understanding via kinetic studies and calculations unravelling the relevant steps along the catalytic cycle of these multicomponent reactions (with ESR8)
3. Improved catalytic performance upon catalyst immobilization

Planned secondments:

• SU to Prof. Martín-Matute (3 months): Synthesis and evaluation of catalytic activity for immobilized MOF-supported catalysts (with ESR3).
• Industrial secondment to HT, Dr. Taarning (2 months): Industrial catalyst implementation and insights into heterogeneous zeolite chemistry.

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Enrolment in Doctoral degree(s): University of Zurich, Switzerland

Principal Supervisor: Prof. Cristina Nevado (UZH)