Project 7

Multicomponent functionalization of π-systems incorporating CO2 (WP2)

Host institution: University of Zurich (UZH), Switzerland
Application Deadline: 31st May 2020
3 PhD year position. Expected start date: Mid 2020.
Remember to read the eligibility criteria here.

Objectives:

  1. Develop a non-precious homogeneous catalytic process for the efficient synthesis of heterocycles using atmospheric CO2 and readily available π-systems as starting materials
  2. Acquire in depth mechanistic understanding on these transformations
  3. Evaluate chiral ligands and Lewis acids for enantioselective formation of heterocycles from CO2.
  4. Immobilize catalysts for an improved performance

Expected results:

  1. Reliable catalytic system for the synthesis of highly functionalized CO2-containing heterocycles from π-systems (alkenes/allenes/alkynes)
  2. Mechanistic understanding via kinetic studies and calculations unravelling the relevant steps along the catalytic cycle of these multicomponent reactions (with ESR8)
  3. Improved catalytic performance upon catalyst immobilization

Planned secondments:

  • SU to Prof. Martín-Matute (3 months): Synthesis and evaluation of catalytic activity for immobilized MOF-supported catalysts (with ESR3).
  • Industrial secondment to HT, Dr. Taarning (2 months): Industrial catalyst implementation and insights into heterogeneous zeolite chemistry.
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Enrolment in Doctoral degree(s): University of Zurich, Switzerland

Principal Supervisor: Prof. Cristina Nevado (UZH)